I2/KI-Mediated Oxidative N-N Bond Formation for the Synthesis of 1,5-Fused 1,2,4-Triazoles from N-Aryl Amidines.
Song, Lina; Tian, Xianhai; Lv, Zhigang; Li, Ertong; Wu, Jie; Liu, Yangxue; Yu, Wenquan; Chang, Junbiao.
J Org Chem
; 80(14): 7219-25, 2015 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-26114202
PhI(OCOCF3)2-mediated intramolecular oxidative N-N bond formation: metal-free synthesis of 1,2,4-triazolo[1,5-a]pyridines.
A straightforward, one-pot protocol for the synthesis of fused 3-aminotriazoles.
Practical synthesis of functionalized 1,5-disubstituted 1,2,4-triazole derivatives.
Rapid synthesis of 1,3,5-substituted 1,2,4-triazoles from carboxylic acids, amidines, and hydrazines.
Cu-catalyzed aerobic oxidative cyclization of guanidylpyridines and derivatives.
Highly Enantioselective Nucleophilic Dearomatization of Pyridines by Anion-Binding Catalysis.
C-H bonds as ubiquitous functionality: preparation of multiple regioisomers of arylated 1,2,4-triazoles via C-H arylation.
The syntheses of [(14) C]BMS-823778 for use in a human ADME clinical study and of [(13) CD3 (13) CD2 ]BMT-094817, a stable-isotope labeled standard of a newly detected human metabolite.
Copper-Catalyzed Oxidative C(sp(3))-H Functionalization for Facile Synthesis of 1,2,4-Triazoles and 1,3,5-Triazines from Amidines.
Reactivity of C-Amino-1,2,4-triazoles toward Electrophiles: A Combined Computational and Experimental Study of Alkylation by Halogen Alkanes.